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機械制造行業(yè)是以機械制造技術(shù)為基礎，具有綜合性、系統性的全球化行業(yè)。下面主要以汽車(chē)制造行業(yè)為代表，研究汽車(chē)制造行業(yè)的工藝流程，進(jìn)而探究汽車(chē)制造行業(yè)產(chǎn)生的危險廢物種類(lèi)，如廢機油、廢機油格、廢濾芯等，并研究對各類(lèi)危險廢物量進(jìn)行核算的方法。</span> </p> <p> <span style="font-size:14px;line-height:2;"> <p style="text-align:center;"> <img src="/uploads/202107/60eeb09524eda.jpg" /> <img src="/uploads/202107/60eeb0de11c2a.jpg" alt="" /> </p> </span> </p> <p> <span style="font-size:14px;"><br /> </span> </p> <span style="font-size:14px;"> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong>◆汽車(chē)制造工藝流程◆</strong></span> </p> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong><br /> </strong></span> </p> </span><span style="font-size:14px;"> <span style="line-height:2;">在汽車(chē)制造過(guò)程中，沖壓、焊接、涂裝、總裝為四大核心技術(shù)。</span></span><br /> <span style="font-size:14px;line-height:2;"> （1）沖壓工藝</span><br /> <span style="font-size:14px;line-height:2;"> 沖壓是汽車(chē)制造工序的第一步：首先把用切割機將鋼板切成所需要的大小，然后進(jìn)行沖孔、切邊之類(lèi)的工序，每一個(gè)工件都有一個(gè)模具，再把各模具裝到?jīng)_壓機床上沖壓出各種所需的工件。</span><br /> <span style="font-size:14px;line-height:2;"> 沖壓是根據金屬塑性變形的特質(zhì)，通過(guò)模具與沖壓設備對板料施加壓力，使板料塑性變形或分離，從而獲得所需形狀、尺寸和性能的零件。</span><br /> <span style="font-size:14px;line-height:2;"> 在沖壓工藝中，主要是切割、打磨，因此該工藝中會(huì )用到潤滑油、切削油，在液壓機使用過(guò)程中，會(huì )用到液壓油，而這些有必然會(huì )產(chǎn)生過(guò)量的油，這都屬于廢礦物油類(lèi)。</span><br /> <span style="font-size:14px;line-height:2;"> （2）焊接工藝</span><br /> <span style="font-size:14px;line-height:2;"> 焊接是通過(guò)對兩分離的金屬表面進(jìn)行加熱或者加壓等手段，其達到原子間的結合，最終永久性連接的一種工藝。汽車(chē)制造過(guò)程中，通過(guò)沖壓工藝后的車(chē)身板件通過(guò)焊接過(guò)程形成車(chē)身總成。</span><br /> <span style="font-size:14px;line-height:2;"> 與沖壓車(chē)間類(lèi)似，焊接車(chē)間產(chǎn)生的危險廢物主要是廢礦物油類(lèi)，包括廢潤滑油、液壓油、切削油</span><br /> <span style="font-size:14px;line-height:2;"> （3）涂裝工藝</span><br /> <span style="font-size:14px;line-height:2;"> 涂裝是指將涂料覆于（基底表面）物面上，經(jīng)過(guò)干燥成膜的工藝；或將涂料在被涂物表面擴散開(kāi)的操作。固化的涂料膜稱(chēng)為涂膜或漆膜，有兩層或兩層以上的涂膜組成的復合層稱(chēng)為涂層。</span><br /> <span style="font-size:14px;line-height:2;"> 涂裝工藝產(chǎn)生的主要危險廢物有漆渣：中涂、面漆噴漆漆霧經(jīng)水幕去除后凝結形成；磷化渣：磷化槽底沉渣；廢溶劑：涂裝車(chē)間廢棄清洗溶劑；廢包裝物、容器、油漆桶。</span><br /> <span style="font-size:14px;line-height:2;"> （4）總裝工藝</span><br /> <span style="font-size:14px;line-height:2;"> 總裝就是將車(chē)身、及各設備配件等構成整輛車(chē)的零件裝配起來(lái)生產(chǎn)出整車(chē)的過(guò)程?？傃b是汽車(chē)制造過(guò)程的最終環(huán)節，是把經(jīng)檢驗合格的各類(lèi)零件，按規定的精度標準和技術(shù)要求組合成整車(chē)，并通過(guò)嚴格的檢測程序，確認其是否合格的工藝過(guò)程。</span><br /> <span style="font-size:14px;line-height:2;"> 總裝工藝中產(chǎn)生的危險廢物主要有廢潤滑油、轉向助力油，還有廢過(guò)濾棉（總裝車(chē)間補漆工序漆霧過(guò)濾）。</span><br /> <span style="font-size:14px;line-height:2;"> （5）污水處理工藝</span><br /> <span style="font-size:14px;line-height:2;"> 污水處理工藝并非汽車(chē)制造工藝中的一個(gè)環(huán)節，但作為產(chǎn)生污水的一個(gè)工廠(chǎng)，汽車(chē)制造廠(chǎng)應該有一個(gè)污水處理工藝，來(lái)處理產(chǎn)生的污水。而污水處理站的淤泥，可能含有有毒物質(zhì)、有腐蝕性物質(zhì)，因此污水處理站污泥也是危險廢物。</span><br /> <p> <span style="font-size:14px;line-height:2;"> 在所有工藝中，會(huì )不同程度的用到工人操作，因此，沾有廢油的手套、工作服、擦布等紡織品也是危險廢物。</span> </p> <p> <span style="font-size:14px;"><br /> </span> </p> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong>◆危險廢物種類(lèi)小結◆</strong></span> </p> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong><br /> </strong></span> </p> <p> <span style="font-size:14px;"> 根據上面的分析，汽車(chē)制造行業(yè)的危險廢物一共有八類(lèi)，具體內容對應表見(jiàn)下表：</span> </p> <p> <table style="text-align:center;font-size:14px;width:100%;" cellpadding="2" cellspacing="0" border="1" bordercolor="#000000"> <tbody> <tr> <td style="text-align:center;"> 種類(lèi)<br /> </td> <td style="text-align:center;"> 內容 <br /> </td> </tr> <tr> <td style="text-align:center;width:50%;"> HW06廢溶劑<br /> </td> <td style="text-align:center;"> 涂裝車(chē)間廢棄清洗溶劑<br /> </td> </tr> <tr> <td style="text-align:center;"> HW08廢礦物油<br /> </td> <td style="text-align:center;"> 沖壓車(chē)間、焊裝車(chē)間廢潤滑油、液壓油、切削油；總裝車(chē)間廢潤滑油、轉向助力油<br /> </td> </tr> <tr> <td style="text-align:center;"> HW12廢油漆渣<br /> </td> <td style="text-align:center;"> 中涂、面漆噴漆漆霧經(jīng)水幕去除后凝結形成<br /> </td> </tr> <tr> <td style="text-align:center;"> HW17污泥<br /> </td> <td style="text-align:center;"> 污水處理站污泥<br /> </td> </tr> <tr> <td style="text-align:center;"> HW49廢包裝物、<span style="text-align:center;white-space:normal;">容器</span><br /> </td> <td style="text-align:center;"> 油漆桶、廢空瓶<br /> </td> </tr> <tr> <td style="text-align:center;"> HW49廢過(guò)濾棉<br /> </td> <td style="text-align:center;"> 總裝車(chē)間補漆工序漆霧過(guò)濾，噴漆車(chē)間廢氣設施中過(guò)濾的過(guò)濾棉<br /> </td> </tr> <tr> <td style="text-align:center;"> HW49廢機油格<br /> </td> <td style="text-align:center;"> 機油格<br /> </td> </tr> <tr> <td style="text-align:center;"> HW49含油廢物<br /> </td> <td style="text-align:center;"> 含油抹布、手套 <br /> </td> </tr> <tr> <td style="text-align:center;"> HW49活性炭<br /> </td> <td style="text-align:center;"> 廢氣處理設備中的活性炭 <br /> </td> </tr> <tr> <td style="text-align:center;"> HW09切削液 </td> <td style="text-align:center;"> 礦物油、高有機物和難以降解物質(zhì),廢水為混合廢水<br /> </td> </tr> </tbody> </table> </p> <div style="text-align:center;"> <span style="font-size:14px;"><br /> </span> </div> <span style="font-size:14px;"> <div style="text-align:center;"> </div> </span> <p> <br /> </p> <p style="text-align:center;"> <span style="font-size:14px;"><br /> </span> </p> <br /> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong>◆各類(lèi)危險廢物的核算方法◆</strong></span> </p> <p style="text-align:center;"> <span style="font-size:24px;color:#009900;"><strong><br /> </strong></span> </p> <span style="font-size:14px;"> (1)產(chǎn)排污系數法（漆渣、廢溶劑類(lèi)）</span><br /> <p> <span style="font-size:14px;"> 根據《第一次全國污染源普查工業(yè)污染源產(chǎn)排污系數的核算及系數手冊》，我國工業(yè)污染物產(chǎn)量絕大部分的351個(gè)小類(lèi)行業(yè)，總共分為10個(gè)分冊，其中第九分冊3721項為汽車(chē)整車(chē)制造的產(chǎn)污系數，輕微轎車(chē)及轎車(chē)節選系數表如表所示：</span> </p> <p> <span style="font-size:14px;"><br /> </span> </p> <p> <span style="font-size:14px;"> <table style="width:100%;" cellpadding="0" cellspacing="0" border="1" class="" bordercolor="#009900"> <tbody> <tr> <td style="text-align:center;"> <br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">產(chǎn)品名稱(chēng)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">原料名稱(chēng)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">污染物指標</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">單位</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">產(chǎn)污系數</span><br /> </td> </tr> <tr> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">微型轎車(chē)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">焊材、油漆、稀料</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">油類(lèi)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">HW12（染料、涂料廢物）、HW17（表面處理廢物）、HW08廢機油等</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">千克/輛</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">8.391</span><br /> </td> </tr> <tr> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">轎車(chē)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">焊材、油漆、稀料</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">油類(lèi)</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">HW12（染料、涂料廢物）、HW17（表面處理廢物）、HW08廢機油等</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">千克/輛</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">7.387</span><br /> </td> </tr> </tbody> </table> <br /> </span> </p> <span style="font-size:14px;"> 根據產(chǎn)污系數表，以企業(yè)實(shí)際生產(chǎn)量，便可以計算出污染物的產(chǎn)生量，公式如下：</span><br /> <p> <span style="font-size:14px;"> 污染物產(chǎn)生量=產(chǎn)污系數*產(chǎn)品產(chǎn)量</span> </p> <p> <span style="font-size:14px;"><br /> </span> </p> <span style="font-size:14px;"> （2）磷化池中磷化渣去處及產(chǎn)量核算</span><br /> <span style="font-size:14px;"> 涂裝是汽車(chē)耐腐蝕和裝飾的最經(jīng)濟而有效的方法，而涂裝表面處理的好壞又是直接影響涂層使用壽命和裝飾效果的重要環(huán)節。</span><br /> <span style="font-size:14px;"> 磷化渣的主要成份為FePO4和Zn3(PO4)2,經(jīng)離心脫水后[8]其主要成分為:Zn2+17.8%,Fe2+12.9%,PO3-444. 8%,H2O 23. 1%,Ni2+0. 6%,Ca2+、NO-3等微量。</span><br /> <span style="font-size:14px;"> 磷化渣的排除</span><br /> <span style="font-size:14px;"> 磷化渣是磷化中產(chǎn)生的,槽中渣量過(guò)多會(huì )附著(zhù)在工件上,影響涂膜性能,尤其在噴淋線(xiàn)上沉渣過(guò)多易造成噴嘴堵塞,影響磷化效果,因此磷化渣應及時(shí)排除。</span><br /> <span style="font-size:14px;"> 除渣可采用帶式過(guò)濾機、板框壓濾機、真空過(guò)濾機等,將磷化渣收集起來(lái)形成渣餅,以便進(jìn)一步處理。</span><br /> <br /> <span style="font-size:14px;"> （3）廢礦物油(HW08)去處及核算方法</span><br /> <span style="font-size:14px;"> 廢礦物油的成因：</span><br /> <span style="font-size:14px;"> 被外來(lái)雜質(zhì)污染；吸水；熱分解；氧化；被燃料油稀釋?zhuān)?/span><br /> <span style="font-size:14px;"> 廢礦物油的處置方式：</span><br /> <span style="font-size:14px;"> 再生利用: 從廢油的組成看, 變質(zhì)物和雜質(zhì)在廢油中只占少部分, 大約為 1%～25%, 其余 99%～75%都是有用成分。因此, 廢礦物油只要經(jīng)過(guò)一定的處理, 就可以再生成為有用油。國家環(huán)保局發(fā)布了《危險廢物污染防治技術(shù)政策》, 其中明確指出: 對于廢礦物油類(lèi), 禁止將廢礦物油任意拋灑、掩埋或倒入下水道及用作建筑脫模油, 鼓勵采用新技術(shù)對廢油進(jìn)行回收利用。</span><br /> <p> <span style="font-size:14px;"> 核算方法：</span> </p> <p> <span style="font-size:14px;"><br /> </span> </p> <p> <span style="font-size:14px;"> <table style="text-align:center;width:100%;" cellpadding="0" cellspacing="0" border="1" class="" bordercolor="#009900"> <tbody> <tr> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">產(chǎn)品</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">污染物指標</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">單位</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">產(chǎn)污系數</span><br /> </td> </tr> <tr> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">機加件</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">HW09（廢乳化液）、HW08（廢礦物油）等</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">千克/噸-原料</span><br /> </td> <td style="text-align:center;"> <span style="font-size:14px;white-space:normal;">3.462</span><br /> </td> </tr> </tbody> </table> </span> </p> <p style="text-align:center;"> <span style="font-size:14px;"><br /> </span> </p> <p> <span style="font-size:14px;"> 根據產(chǎn)污系數表，以企業(yè)實(shí)際生產(chǎn)量，便可以計算出污染物的產(chǎn)生量，公式如下：</span> </p> <span style="font-size:14px;"> 污染物產(chǎn)生量=產(chǎn)污系數*產(chǎn)品產(chǎn)量。</span><br /> <span style="font-size:14px;"> 其他加工工藝中，廢礦物油產(chǎn)量較少。</span><br /> </div> <div id="iivpcxe" class="page-show-box"> <dt>方案優(yōu)勢</dt> <div style="text-align:center;"> <img src="/uploads/202011/5fae318b011e3.jpg" width="900" height="449" title="沃藤環(huán)保優(yōu)勢" alt="沃藤環(huán)保優(yōu)勢" /><br /> </div> </div> <div id="vodsao0" class="page-show-box"> <dt>服務(wù)流程</dt> <div style="text-align:center;"> <img src="/uploads/202106/60c037ad347c4.jpg" alt="" /><br /> </div> </div> <div id="ccwo8e3" class="page-show-box"> <dt>成功案例</dt> <div id="aakerao" class="rela-case"> <ul> <li><a href="/qitazhizaoyeweifeichuli45/45-60.html"> <span><img 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